Hi Leon, I'm so glad you suggested a second opinion....
Took the car down to Kwikfit and they hooked it up to their machine.
40mins and £49 later all done!
Apparently there was only 2ml of oil in the compressor and this was the likely cause of stalling etc.
Their aircon machine is fully automatic, all they do is connect it up and enter the car make and model.
It extracts all the old gas and moisture, does a leak test, checks compressor oil and if all is OK, fills the system with the correct amount of refrigerant.
Never been a fan of Kwiksh8t myself but they do seem to have this particular service sorted.
I think I'm going to take the wifes' Smart there next - she was complaining that it wasn't blowing cold.
Russ