Many thanks to both of you.
sgould -
Clean water - lots of it. I am ringing the water out of the deadening material. Both front footwells affected (as I discovered this morning). Coolant level has been fine over the years, so that hopefully discounts the heater matrix. No sunroof.
I will try the talc test, but amount of water is ridiculous at the moment, and have run out of newspapers for the mo. I am presuming this has been going on for some time - it may have been more difficult to demist last winter, but I don't use on a daily basis, so didn't think that much of it. I have a UV lamp, so might try that if I run out of options.
Door seals are a little perished, but nothing split or hanging off.
audax -
I have the seats unbolted, to release the front footwell carpet sections. Will have a look in the back. I was at one point hoping that it was the floorpan end of the AC drain pipes, as the drivers side connection was pretty weak into the grommet leading out of the car, and wet around there. Then had a look at the passenger side, and unfortunately this area was bone dry. Saturation is worst nearest bulkhead on both sides - the deadening material with a 'hard shell' in the pedal box area is soaked underneath, so this also needs drying out before I can progress. Are the rear footwells slightly higher then? Car has been parked more or less level for years.
Might take a while to get to the bottom of this...